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Synthesis and characterization of ML and ML2 metal complexes with amino acid substituted bis(2-picolyl)amine ligands


Škalamera, Đani; Sanders, Ernest; Vianello, Robert; Maršavelski, Aleksandra; Pevec, Andrej; Turel, Iztok; Kirin, Srećko I.
Synthesis and characterization of ML and ML2 metal complexes with amino acid substituted bis(2-picolyl)amine ligands // Dalton transactions, 45 (2016), 7; 2845-2858 doi:10.1039/C5DT03387J (međunarodna recenzija, članak, znanstveni)


Naslov
Synthesis and characterization of ML and ML2 metal complexes with amino acid substituted bis(2-picolyl)amine ligands

Autori
Škalamera, Đani ; Sanders, Ernest ; Vianello, Robert ; Maršavelski, Aleksandra ; Pevec, Andrej ; Turel, Iztok ; Kirin, Srećko I.

Izvornik
Dalton transactions (1477-9226) 45 (2016), 7; 2845-2858

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Bis(2picolyl)amine ; stereochemistry ; quantum-chemical calculations ; zinc complexes

Sažetak
Metal complexes with ML or ML2 stoichiometry have been isolated in the reaction of Zn(NO3)2, ZnBr2 or M(NO3)2 / NaBF4, M = Zn(II), Co(II) or Ni(II), with either amino acid or amine substituted tridentate nitrogen ligands based on bis(2picolyl)amine (bpa) or bis(2-quinaldyl)amine (bqa). The stoichiometry (M : L = 1:1 or 1:2) and stereochemistry (mer, transfac or cis-fac) of the products have been studied by NMR spectroscopy, X-ray single crystal analysis and quantum-chemical calculations with an implicit SMD solvation model.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
HRZZ-IP-2014-09-1461 - Minimalni umjetni enzimi: Proširenje primjene posredne indukcije na nove supstrate i nove asimetrične reakcije (Srećko Kirin, )
HRZZ-IP-2014-09-3386 - Dizajn i sinteza novih dušikovih heterocikličkih fluorofora i fluorescentnih nanomaterijala kao kemijskih senzora za pH i metalne ione (Robert Vianello, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


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