Femtosecond time-resolved two-photon photoemission spectroscopy of C6H5X/D2O/Cu(111) (CROSBI ID 623814)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Agarwal, Ishita ; Avigo, Isabella ; Sayed, Abdul Samad ; Ligges, Manuel ; Mikšić Trontl, Vesna ; Zhou, Ping ; Bovensiepen, Uwe
engleski
Femtosecond time-resolved two-photon photoemission spectroscopy of C6H5X/D2O/Cu(111)
The electron dynamics at a metal-molecule interface is studied with time-resolved two-photon photoemission. We report here energies, workfunction changes and lifetimes of excited electronic states in amorphous D2O/Cu(111) and coadsorbed C6H5F systems after optical excitation with 3.8 eV + 1.9 eV femtosecond laser pulses. We observe a decrease in lifetime of the solvated electron state from 90±5 fs for bare D2O to 60±5 fs for coadsorbed C6H5F. Further, after a total estimated exposure to 0.5×106 photons per C6H5F molecule, a workfunction change of 200±50 meV was observed. Due to the absence of photo-induced workfunction changes in the single stack D2O/Cu(111) and C6H5F/Cu(111), this change is concluded to be mediated by solvated electrons. Additional experiments on C6H5Cl/D2O/Cu(111) were performed and an even larger photoinduced workfunction change was observed. The increase in workfunction is explained by the formation of F−/Cl− as a photo-chemical dissociation product. We conclude to have identified the charge transfer to C6H5F(/Cl) and a fingerprint of its photoinduced dissociation. Future experiments aim to systematically change the UV photon energy and the molecule acceptor level.
photoemission spectroscopy
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o prilogu
2015.
objavljeno
Podaci o matičnoj publikaciji
Podaci o skupu
Verhandlungen der Deutschen Physikalischen Gesellschaft. 2015
poster
15.03.2015-20.03.2015
Berlin, Njemačka