engleski

Simulation of influence of variable diffusion coefficient in cyclic voltammetry

A model of electrode reaction of solid compound that includes an insertion of cations from the solution is developed and the influence of concentration-dependent diffusion coefficient in cyclic voltammetry is investigated theoretically. Generally, the form of response does not change significantly, but in some cases the cathodic peak may split in two.

Cyclic voltammetry; diffusion coefficient; solid-state electrode reactions; insertion compounds

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