Electronic structure of antibiotic erythromycin (CROSBI ID 214350)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Novak, Igor ; Kovač, Branka
engleski
Electronic structure of antibiotic erythromycin
The electronic structure of erythromycin A(ERYMA) molecule has been studied by UV photoelectron spectroscopy and assigned (in the low ionization energy region only) by empirical arguments. The two orbitals with highest energy (lowest ionization energy) are localized on the nitrogen of the desosamine sugar functional group and on the ester group of macrolide (lactone) ring. We discuss how these orbital energies can help to rationalize the known mode of binding of ERYMA to their biological receptors.
Photoelectron spectroscopy; Erythromycin
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Podaci o izdanju
138
2015.
550-552
objavljeno
1386-1425
10.1016/j.saa.2014.11.076