izvor podataka: crosbi
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High pressure promoted exchange of guests from hemicarceplexes (CROSBI ID 214025)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Vazdar, Mario ; Mitchell, Anthony, S. ; Warrener, Ronald, N. ; Margetić, Davor
High pressure promoted exchange of guests from hemicarceplexes // Tetrahedron, 2015 (2015), 4; 550-553. doi: 10.1016/j.tet.2014.12.040
Podaci o odgovornosti
Vazdar, Mario ; Mitchell, Anthony, S. ; Warrener, Ronald, N. ; Margetić, Davor
engleski
High pressure promoted exchange of guests from hemicarceplexes
Application of extremely high pressures on dimethylacetamide (DMA) hemicarceplexes promotes DMA extrusion and re-placement with a solvent molecule at room temperature. Molecular dynamics study of decomplexation of hemicarcerands indicates that favored mechanistic process involves a single-step exchange of DMA with a solvent molecule.
hemicarceplexes; high pressure; molecular dynamics; NMR
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