engleski

Theory of square wave voltammetry of three step electrode reaction

A theory of square wave voltammetry of three step electrode reaction of amalgam forming ions is developed for a thin mercury film electrode. It is assumed that the first and the second electron transfers are kinetically controlled while the third one is reversible and that the intermediates are thermodynamically unstable. The responses to the cathodic and anodic scan directions are analyzed.

Square wave voltammetry; three step electrode reaction; transfer coefficient; theory.

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