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Morphology and mechanical properties of iPP/silica composites modified with (styrene-b-ethylene-co-butylene-b-styrene) grafted with maleic anhydride


Pustak, Anđela; Denac, Matjaž; Leskovac, Mirela; Švab, Iztok; Vojko, Musil; Šmit, Ivan
Morphology and mechanical properties of iPP/silica composites modified with (styrene-b-ethylene-co-butylene-b-styrene) grafted with maleic anhydride // Polymer-plastics technology and engineering, 54 (2015), 6; 647-660 doi:10.1080/03602559.2014.979495 (međunarodna recenzija, članak, znanstveni)


Naslov
Morphology and mechanical properties of iPP/silica composites modified with (styrene-b-ethylene-co-butylene-b-styrene) grafted with maleic anhydride

Autori
Pustak, Anđela ; Denac, Matjaž ; Leskovac, Mirela ; Švab, Iztok ; Vojko, Musil ; Šmit, Ivan

Izvornik
Polymer-plastics technology and engineering (0360-2559) 54 (2015), 6; 647-660

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Polypropylene Composites; Morphology; Interfacial properties; Mechanical properties

Sažetak
The effects of different silica grades and elastomer content on interfacial properties, morphology and mechanical properties of polypropylene/silica 96/4 composites modified with added 5, 10, 15, and 20 % of poly(styrene-b-ethylene-co-butylene-b-styrene) grafted with maleic anhydride (SEBS-g-MA) were investigated. The iPP/silica/SEBS-g-MA composites were designed by adding four silica fillers differing in size (nano- vs. micro-) and in surface properties (hydrophilic vs. hydrophobic) and SEBS-g-MA that was used as a proven effective impact modifier and compatibilizer simultaneously. The morphology of every composite was a spectrum of several morphologies rather than one exclusive morphology. Good concordance between observed and predicted morphology indicated that the morphology of a particular composite was controlled primarily by interfacial properties. Tensile and impact properties were influenced primarily by competitive effects of a stiff filler and tough SEBS-g-MA elastomer. Increased impact strength and strain at break designed by adding of SEBS-g-MA indicated a significant overcoming of the elastomeric toughening effect in relation to the filler's stiffening effect.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo



POVEZANOST RADA


Projekt / tema
098-0982904-2955 - Odnosi struktura-svojstvo modificiranih polimernih materijala (Irina Pucić, )
125-1252971-2575 - Inženjerstvo površina i međupovršina nanočestica u adhezijskim nanomaterijalima (Mirela Leskovac, )

Ustanove
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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