Electrochemical characterization of (1E)-1-N- {;;[4-(4-{;;[(E)-N-(4- aminophenyl)carboxyimidoyl]phenoxy};;butoxy) phenyl] methilidene};; benzene -1, 4-diamine (CROSBI ID 615288)
Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | međunarodna recenzija
Podaci o odgovornosti
Šter, Anamarija ; Medvidović-Kosanović, Martina ; Balić, Tomislav ; Ćurić, Iva ; Mihaljević-Jurić, Paula
engleski
Electrochemical characterization of (1E)-1-N- {;;[4-(4-{;;[(E)-N-(4- aminophenyl)carboxyimidoyl]phenoxy};;butoxy) phenyl] methilidene};; benzene -1, 4-diamine
Oxido-reduction properties of a newly synthesized Schiff base were investigated by cyclic voltammetry and differential pulse voltammetry. Measurements were conducted in a three electrode voltammetric cell in a non- aqueous media. Glassy carbon was used as a working electrode, platinum wire as counter electrode and non-aqueous Ag/Ag+ electrode as a reference electrode. Inert atmosphere was acomplished by system purging with high purity argon Ar 5 (Ar = 99, 999 %), before each measurement. Cyclyc voltammograms revealed one oxidation and one reduction peak of the investigated Schiff base (Ep, a = 0, 44 V and Ep, k = 0, 39 V), which both increased with increasing concentration (c = 3, 1 •10-5 mol dm-3... 1, 25 •10-4 mol dm-3) and scan rate (ν = 50...300 mV/s) [1] [2]. Differential pulse voltammetry showed one oxidation peak Ep, a = 0, 41 V, which also increased with increasing concentration [3].
Schiff base ; electrochemistry ; oxidation ; reduction ; voltammetry
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Podaci o prilogu
39-39.
2014.
objavljeno
Podaci o matičnoj publikaciji
15th Ružička days "Today science - tommorow industry"
Šubarić, Drago
Osijek: Prehrambeno tehnološki fakultet Sveučilišta Josipa Jurja Strossmayera u Osijeku
978-953-7005-34-4
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15th Ružička days "TODAY SCIENCE – TOMMOROW INDUSTRY"
poster
11.09.2014-12.09.2014
Vukovar, Hrvatska