A cation-directed two-component cascade approach to enantioenriched pyrroloindolines (CROSBI ID 209664)
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Podaci o odgovornosti
Wolstenhulme, Jamie R. ; Cavell, Alex ; Gredičak, Matija ; Driver, Russell W. ; Smith, Martin D.
engleski
A cation-directed two-component cascade approach to enantioenriched pyrroloindolines
A cascade approach to complex pyrroloindolines bearing all-carbon quaternary stereocentres has been developed. This two-component process uses a chiral ammonium salt to control diastereo- and enantioselectivity in the addition of isocyanides to functionalized alkenes to afford pyrroloindolines with up to three stereocentres. A mechanistic proposal involving intramolecular hydrogen bond activation of the isocyanide is described.
organocatalysis; pyrroloindoline; phase-transfer catalysis; cascade reaction
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