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A 3D Oxalate-Based Network as a Precursor for the CoMn2O4 Spinel : Synthesis and Structural and Magnetic Studies


Habjanič, Jelena; Jurić, Marijana; Popović, Jasminka; Molčanov, Krešimir; Pajić, Damir
A 3D Oxalate-Based Network as a Precursor for the CoMn2O4 Spinel : Synthesis and Structural and Magnetic Studies // Inorganic chemistry, 53 (2014), 18; 9633-9643 doi:10.1021/ic501134y (međunarodna recenzija, članak, znanstveni)


Naslov
A 3D Oxalate-Based Network as a Precursor for the CoMn2O4 Spinel : Synthesis and Structural and Magnetic Studies

Autori
Habjanič, Jelena ; Jurić, Marijana ; Popović, Jasminka ; Molčanov, Krešimir ; Pajić, Damir

Izvornik
Inorganic chemistry (0020-1669) 53 (2014), 18; 9633-9643

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Heterometallic oxalate-based compound; spinel structure; magetic study

Sažetak
A novel heterometallic oxalate-based compound of the formula {; ; ; ; ; ; ; [Co(bpy)3][Mn2(C2O4)3]·H2O}; ; ; ; ; ; ; n (1 ; bpy = 2, 2′-bipyridine) was synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction (XRD), and magnetization measurement. The molecular structure of 1 is made of a three- dimensional (3D) anionic network, [Mn2(C2O4)3]n2n–, and tris-chelated cations [Co(bpy)3]2+ occupying the vacancies of the framework. Splitting between the zero-field-cooled (ZFC) and field-cooled (FC) branches of susceptibility below the small peak at 13 K indicates magnetic ordering. Compound 1 was used as a single-source precursor for the formation of the mixed-metal oxide CoMn2O4. This conversion via thermal decomposition was explored by thermal analysis (TGA and DTA), IR spectroscopy, powder XRD, and magnetic susceptibility measurement. From refined structural parameters, it could be seen that the spinel obtained by the thermal treatment of 1 at 800 °C is characterized by the inversion parameter δ = 21%, and therefore the structural formula at room temperature can be written as tet[Co0.79Mn0.21]oct[Co0.105Mn0.895]2O4. The temperature dependence of magnetization for CoMn2O4 points to at least three magnetic phases: the ferrimagnetic state is observed below 83 K, and up to 180 K blocking of the magnetic moments of nanocrystallites of 31 nm appears, transforming to paramagnetic-like behavior above 180 K. Microstructural characterization of the CoMn2O4 sample was carried out by means of XRD line- broadening analysis.

Izvorni jezik
Engleski

Znanstvena područja
Fizika, Kemija



POVEZANOST RADA


Projekt / tema
098-0982904-2946 - Višenuklearni metalni sustavi: sinteza i svojstva (Berislav Perić, )
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Marija Luić, )
119-1191458-1017 - Nanomagneti (Krešo Zadro, )

Ustanove
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus
  • MEDLINE


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