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New Fe-Ta and Co-Ta oxalate complexes: structural characterization and thermal behaviour – formation of mixed-metal oxides


Androš, Lidija; Jurić, Marijana; Popović, Jasminka; Planinić, Pavica
New Fe-Ta and Co-Ta oxalate complexes: structural characterization and thermal behaviour – formation of mixed-metal oxides // RSC Advances, 4 (2014), 70; 37051-37060 doi:10.1039/C4RA05855K (međunarodna recenzija, članak, znanstveni)


Naslov
New Fe-Ta and Co-Ta oxalate complexes: structural characterization and thermal behaviour – formation of mixed-metal oxides

Autori
Androš, Lidija ; Jurić, Marijana ; Popović, Jasminka ; Planinić, Pavica

Izvornik
RSC Advances (2046-2069) 4 (2014), 70; 37051-37060

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Tantalum; oxalate; molecular precursors for oxides; FeTaO4; CoTa2O6; Co4Ta2O9

Sažetak
Two novel heterometallic oxalate-based compounds, [M(phen)3][Ta(OC2H5)(C2O4)3]•H2O [M = Fe (1), Co (2) ; phen = 1, 10-phenanthroline] were synthesized by using an (oxalato)tantalate(V) aqueous solution as a source of complex anions. As a result of the presence of ethanol in the reaction mixture, ethoxy group coordinated to tantalum(V) and the [Ta(OC2H5)(C2O4)3]2– anion was isolated in the crystalline products. The obtained compounds were characterized by means of IR spectroscopy, X-ray single-crystal diffraction and thermal analysis. Both compounds were investigated as possible molecular precursors for the mixed-metal oxides. Thermal decomposition residues of the compounds at different heating temperatures (800, 1000, 1200 ºC) were analyzed by powder X-ray diffraction. When 1 was heated up to 800–1200 °C the mixed-metal oxide FeTaO4, of different crystallite sizes, formed. Thermal decomposition residue of 2, heat-treated up to 1000 °C, contained an up to now non-investigated mixed-metal oxide, Co4Ta2O9, along with the better known mixed-metal oxide CoTa2O6. Co4Ta2O9 was for the first time structurally characterized: a structure is composed of i) layers containing hexagonally arranged CoO6 octahedra and ii) layers where both CoO6 and TaO6 octahedra form a hexagonal assembly.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982904-2946 - Višenuklearni metalni sustavi: sinteza i svojstva (Berislav Perić, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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