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Pregled bibliografske jedinice broj: 697940

The synthesis and structural characterization of peralkylated triguanide superbases


Štrukil, Vjekoslav; Lekšić, Edislav; Meštrović, Ernest; Eckert-Maksić, Mirjana
The synthesis and structural characterization of peralkylated triguanide superbases // Australian journal of chemistry, 67 (2014), 7; 1129-1133. doi:10.1071/CH14233 (članak, znanstveni)


Naslov
The synthesis and structural characterization of peralkylated triguanide superbases

Autori
Štrukil, Vjekoslav ; Lekšić, Edislav ; Meštrović, Ernest ; Eckert-Maksić, Mirjana

Izvornik
Australian journal of chemistry (0004-9425) 67 (2014), 7; 1129-1133

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Organic superbases; triguanides

Sažetak
Organic superbases derived from a peralkylated triguanide framework have been synthesised in a coupling reaction between monosubstituted guanidines and a Vilsmeier salt. Single crystal X-ray diffraction analysis of the chloride salt allowed the structural characterisation of the benzyl derivative for the first time and revealed an effective delocalisation of the positive charge despite significant distortion of the triguande cation planarity. With the calculated gas phase basicity ranging from 262 to 265 kcal mol–1 and pKa values in acetonitrile between 28 and 30, these compounds have been evaluated as potential organocatalysts in the transesterification reaction of vegetable oil.

Projekt / tema
098-0982933-2920 - Organski i bioorganski procesi u osnovnom i elektronski pobuđenim stanjima (Mirjana Maksić)

Izvorni jezik
Engleski

Rad je citiran u bazama podataka
WoSCC, Current Contents, Science Citation Index Expanded Index, Scopus

Znanstvena područja
Kemija