engleski

Theory of square wave voltammetry of amalgam forming ions at spherical electrodes

A theoretical model of reversible reduction of amalgam forming ion on stationary mercury drop electrode is developed for square wave voltammetry. The dependence of dimensionless net peak current on the dimensionless inverse electrode radius is investigated. This relationship is not linear, but it is a curve with two asymptotes. These results apply to electroanalytical measurements at spherical microelectrodes.

square wave voltammetry; spherical electrodes; theory; microelectrode

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