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Pregled bibliografske jedinice broj: 683973

Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom


Vuk, Dragana; Kikaš, Ilijana; Molčanov, Krešimir; Horváth, Ottó; Škorić, Irena
Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom // Journal of molecular structure, 1063 (2014), 83-91 doi:10.1016/j.molstruc.2014.01.055 (međunarodna recenzija, članak, znanstveni)


Naslov
Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom

Autori
Vuk, Dragana ; Kikaš, Ilijana ; Molčanov, Krešimir ; Horváth, Ottó ; Škorić, Irena

Izvornik
Journal of molecular structure (0022-2860) 1063 (2014); 83-91

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
photocatalytic oxygenation; porphyrins; benzobicyclo[3.2.1]octadienes; thiophene derivative; furan derivative; heteroatom impact

Sažetak
Photocatalytic oxygenations of a furan and two thiophene derivatives of benzobicyclo[3.2.1]octadiene have been realized by using anionic and cationic manganese(III) porphyrins as catalysts. The replace of oxygen with sulfur in the heteroaromatic ring considerably decreased the reactivity of these heterocyclic compounds, probably due to the increased aromaticity. The end-products of the oxygenation of the thiophene derivatives significantly deviated from most of those formed from the corresponding furan compounds ; the lower reactivity of the thiophene ring enhanced the role of the out-of-ring carbon atom in the reaction pathways. Besides, deviating from the behavior of the furan compounds, the types of the end-products formed from the corresponding thiophene derivatives did not depend on the charge of the photocatalyst, neither on the oxygen concentration. However, also in this case, the position of the heteroatom in the aromatic ring strongly affects the formation of the end- products.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Marija Luić, )
125-0982933-2926 - Heteropolicikli, strukturne osnove za bioaktivne spojeve. Sinteza i fotokemija (Irena Škorić, )

Ustanove
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Profili:

Avatar Url Krešimir Molčanov (autor)

Avatar Url Irena Škorić (autor)

Avatar Url Dragana Vuk (autor)

Citiraj ovu publikaciju

Vuk, Dragana; Kikaš, Ilijana; Molčanov, Krešimir; Horváth, Ottó; Škorić, Irena
Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom // Journal of molecular structure, 1063 (2014), 83-91 doi:10.1016/j.molstruc.2014.01.055 (međunarodna recenzija, članak, znanstveni)
Vuk, D., Kikaš, I., Molčanov, K., Horváth, O. & Škorić, I. (2014) Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom. Journal of molecular structure, 1063, 83-91 doi:10.1016/j.molstruc.2014.01.055.
@article{article, year = {2014}, pages = {83-91}, DOI = {10.1016/j.molstruc.2014.01.055}, keywords = {photocatalytic oxygenation, porphyrins, benzobicyclo[3.2.1]octadienes, thiophene derivative, furan derivative, heteroatom impact}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2014.01.055}, volume = {1063}, issn = {0022-2860}, title = {Functionalization of the benzobicyclo[3.2.1]octadiene skeleton via photocatalytic oxygenation of thiophene and furan derivatives: the impact of the type and position of the heteroatom}, keyword = {photocatalytic oxygenation, porphyrins, benzobicyclo[3.2.1]octadienes, thiophene derivative, furan derivative, heteroatom impact} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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