engleski

Square-wave voltammetry of two-step electrode reaction

A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed and a special case of thermodynamically unstable intermediate is analyzed. If the first electron transfer is slower than the second one, the transfer coefficients can be determined by the application of cathodic and anodic scan directions.

two-step electrode reactions; square-wave voltammetry; Transfer coefficients

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