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Pregled bibliografske jedinice broj: 646223

Signal processing and measurement automation in electroanalysis


Omanović, Dario; Pižeta, Ivanka; Garnier, Cedric
Signal processing and measurement automation in electroanalysis // Book of abstracts
Šibenik, Hrvatska, 2012. (pozvano predavanje, nije recenziran, sažetak, znanstveni)


CROSBI ID: 646223 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Signal processing and measurement automation in electroanalysis

Autori
Omanović, Dario ; Pižeta, Ivanka ; Garnier, Cedric

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of abstracts / - , 2012

Skup
GEOTRACES and Voltammetry - a COST801 workshop

Mjesto i datum
Šibenik, Hrvatska, 06-09.10.2012

Vrsta sudjelovanja
Pozvano predavanje

Vrsta recenzije
Nije recenziran

Ključne riječi
voltamemtry; electroanalysis; signal processing

Sažetak
In electroanalysis, the main focus of signal processing is the transformation of measured data, in order to conveniently extract the appropriate information (e.g. peak intensity). Such mathematical transformation should minimize the distortion of the original information as much as possible. The most frequently employed signal processing routines are the noise removal (digital smoothing), the baseline correction, the signal intensity determination, the overlapped peaks separation, and various ways of mathematical manipulations (e.g. differentiation, integration). Usually, voltammetric curves are treated one at the time using the best “decision maker” method known as the “expert eye”. The produced effect depends mainly on experience of the operator and the capabilities of the software used. Once the sequence of treatment procedures is defined, an automatic processing method could be applied. Having this option available within the software, would be of great advantage for electroanalytical applications with a large number of curves. However, software packages supplied with electrochemical instrumentation usually do not provide such a functionality (or it is very limited), and researchers are referred to specialized independent data treatment software packages. The signal-to-noise ratio and the signal-to-background relationships are the two major voltammetric curve characteristics that should be improved after signal processing. Digital filtering (smoothing) and baseline corrections are applied for this purpose. These two steps become more important as the electrochemical analysis approaches the limit of quantification of the applied method (Fig. 1). Transformation of voltammetric curves by a derivative function is an optional approach that can eliminate the need to use the baseline correction method, which is user dependent (subjective). However, it is very important for the user to identify the capabilities and limitations of the used processing routines, as an inappropriate use could result in incorrect final results. Various effects on the final result produced by signal processing and mathematical transformations will be demonstrated through examples of determination of unknown analyte concentration using the standard addition method. Several options for the improvement of analysis accuracy and precision, based on the internal standard method, will be presented. The consequences of improper signal processing in environmental studies will be illustrated on the example of determination of copper complexing capacity. Guidelines of signal processing and the experimental design will be provided. A home-made automatic station for the voltammetric analyses of trace metals will be presented. It consists of the voltammetric analyser, measurement electrode stand, sample changer, peristaltic pump and burette system for addition of standards and chemical. New software which manages preparation of the measurement procedures and subsequent metal quantification was developed.

Izvorni jezik
Engleski

Znanstvena područja
Geologija, Kemija



POVEZANOST RADA


Projekti:
098-0982934-2720 - Međudjelovanja oblika tragova metala u vodenom okolišu (Pižeta, Ivanka, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Ivanka Pižeta (autor)

Avatar Url Dario Omanović (autor)


Citiraj ovu publikaciju:

Omanović, Dario; Pižeta, Ivanka; Garnier, Cedric
Signal processing and measurement automation in electroanalysis // Book of abstracts
Šibenik, Hrvatska, 2012. (pozvano predavanje, nije recenziran, sažetak, znanstveni)
Omanović, D., Pižeta, I. & Garnier, C. (2012) Signal processing and measurement automation in electroanalysis. U: Book of abstracts.
@article{article, author = {Omanovi\'{c}, Dario and Pi\v{z}eta, Ivanka and Garnier, Cedric}, year = {2012}, keywords = {voltamemtry, electroanalysis, signal processing}, title = {Signal processing and measurement automation in electroanalysis}, keyword = {voltamemtry, electroanalysis, signal processing}, publisherplace = {\v{S}ibenik, Hrvatska} }
@article{article, author = {Omanovi\'{c}, Dario and Pi\v{z}eta, Ivanka and Garnier, Cedric}, year = {2012}, keywords = {voltamemtry, electroanalysis, signal processing}, title = {Signal processing and measurement automation in electroanalysis}, keyword = {voltamemtry, electroanalysis, signal processing}, publisherplace = {\v{S}ibenik, Hrvatska} }




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