Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 641887

Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes.


Jadreško, Dijana; Zelić, Marina
Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes. // Journal of electroanalytical chemistry, 707 (2013), 20-30 doi:10.1016/j.jelechem.2013.08.011 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 641887 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes.

Autori
Jadreško, Dijana ; Zelić, Marina

Izvornik
Journal of electroanalytical chemistry (1572-6657) 707 (2013); 20-30

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
cyclic multi pulse voltammetry; cyclic differential multi pulse voltammetry; cyclic square-wave voltammetry; excitation signal; kinetics; theory.

Sažetak
A comparative, theoretical and experimental, analysis of reversible and kinetically controlled electrode reactions by cyclic multi pulse voltammetry (CMPV), cyclic differential multi pulse voltammetry (CDMPV) and cyclic square-wave voltammetry (CSWV) is presented. The cyclic multipulse voltammetric techniques enable faster and more complete characterization of the electrode processes, comparing with classical multipulse voltammetric techniques. Electron transfer coefficients (α and β), i.e. symmetry of the electron transfer reaction can be estimated by visual inspection of the proper cyclic multipulse voltammogram. Their values, as well as the standard rate constant of a simple electrode reaction Ox + ne- Red, can be determined from the slopes of linear dependences of characteristic (half wave or peak) cathodic and anodic potentials on the logarithm of pulse duration in CMPV and CDMPV, or logarithm of frequency in CSWV. The criteria for recognition of kinetically controlled electrode reactions by cyclic multipulse voltammetric techniques are given.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Marina Zelić (autor)

Avatar Url Dijana Jadreško (autor)

Citiraj ovu publikaciju:

Jadreško, Dijana; Zelić, Marina
Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes. // Journal of electroanalytical chemistry, 707 (2013), 20-30 doi:10.1016/j.jelechem.2013.08.011 (međunarodna recenzija, članak, znanstveni)
Jadreško, D. & Zelić, M. (2013) Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes.. Journal of electroanalytical chemistry, 707, 20-30 doi:10.1016/j.jelechem.2013.08.011.
@article{article, author = {Jadre\v{s}ko, Dijana and Zeli\'{c}, Marina}, year = {2013}, pages = {20-30}, DOI = {10.1016/j.jelechem.2013.08.011}, keywords = {cyclic multi pulse voltammetry, cyclic differential multi pulse voltammetry, cyclic square-wave voltammetry, excitation signal, kinetics, theory.}, journal = {Journal of electroanalytical chemistry}, doi = {10.1016/j.jelechem.2013.08.011}, volume = {707}, issn = {1572-6657}, title = {Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes.}, keyword = {cyclic multi pulse voltammetry, cyclic differential multi pulse voltammetry, cyclic square-wave voltammetry, excitation signal, kinetics, theory.} }
@article{article, author = {Jadre\v{s}ko, Dijana and Zeli\'{c}, Marina}, year = {2013}, pages = {20-30}, DOI = {10.1016/j.jelechem.2013.08.011}, keywords = {cyclic multi pulse voltammetry, cyclic differential multi pulse voltammetry, cyclic square-wave voltammetry, excitation signal, kinetics, theory.}, journal = {Journal of electroanalytical chemistry}, doi = {10.1016/j.jelechem.2013.08.011}, volume = {707}, issn = {1572-6657}, title = {Cyclic multipulse voltammetric techniques. Part I: Kinetics of electrode processes.}, keyword = {cyclic multi pulse voltammetry, cyclic differential multi pulse voltammetry, cyclic square-wave voltammetry, excitation signal, kinetics, theory.} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font