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Pregled bibliografske jedinice broj: 638168

Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour


Vuk, Dragana; Potroško, Dalia; Šindler-Kulyk, Marija; Marinić, Željko; Molčanov, Krešimir; Kojić-Prodić, Biserka; Škorić, Irena
Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour // Journal of molecular structure, 1051 (2013), 1-14 doi:10.1016/j.molstruc.2013.07.052 (međunarodna recenzija, članak, znanstveni)


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Naslov
Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour

Autori
Vuk, Dragana ; Potroško, Dalia ; Šindler-Kulyk, Marija ; Marinić, Željko ; Molčanov, Krešimir ; Kojić-Prodić, Biserka ; Škorić, Irena

Izvornik
Journal of molecular structure (0022-2860) 1051 (2013); 1-14

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
butadiene ; chlorine ; photochemistry ; reaction mechanism ; spectroscopy

Sažetak
The photochemical behavior of mono- and dichloro- substituted butadiene derivatives was studied at low concentrations. These compounds display diverse photochemical behavior. The -chloro derivatives photocyclize to give six-membered ring photoproducts. p-Chloro-substituted butadienes undergo intramolecular [2+2] cycloaddition followed by formation of benzobicyclic structures. The steric hindrance of chlorine(s) in - position(s) cause a greater deviation from planarity, relative to p-substitution, and shift conformer equilibria and affects the reaction pathways and yields.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
MZOS-098-0982929-2917 - Spektroskopija NMR i modeliranje bioaktivnih molekula (Plavšić, Dejan, MZOS ) ( POIROT)
MZOS-098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Luić, Marija, MZOS ) ( POIROT)
MZOS-125-0982933-2926 - Heteropolicikli, strukturne osnove za bioaktivne spojeve. Sinteza i fotokemija (Škorić, Irena, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Citiraj ovu publikaciju:

Vuk, Dragana; Potroško, Dalia; Šindler-Kulyk, Marija; Marinić, Željko; Molčanov, Krešimir; Kojić-Prodić, Biserka; Škorić, Irena
Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour // Journal of molecular structure, 1051 (2013), 1-14 doi:10.1016/j.molstruc.2013.07.052 (međunarodna recenzija, članak, znanstveni)
Vuk, D., Potroško, D., Šindler-Kulyk, M., Marinić, Ž., Molčanov, K., Kojić-Prodić, B. & Škorić, I. (2013) Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour. Journal of molecular structure, 1051, 1-14 doi:10.1016/j.molstruc.2013.07.052.
@article{article, author = {Vuk, Dragana and Potro\v{s}ko, Dalia and \v{S}indler-Kulyk, Marija and Marini\'{c}, \v{Z}eljko and Mol\v{c}anov, Kre\v{s}imir and Koji\'{c}-Prodi\'{c}, Biserka and \v{S}kori\'{c}, Irena}, year = {2013}, pages = {1-14}, DOI = {10.1016/j.molstruc.2013.07.052}, keywords = {butadiene, chlorine, photochemistry, reaction mechanism, spectroscopy}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2013.07.052}, volume = {1051}, issn = {0022-2860}, title = {Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour}, keyword = {butadiene, chlorine, photochemistry, reaction mechanism, spectroscopy} }
@article{article, author = {Vuk, Dragana and Potro\v{s}ko, Dalia and \v{S}indler-Kulyk, Marija and Marini\'{c}, \v{Z}eljko and Mol\v{c}anov, Kre\v{s}imir and Koji\'{c}-Prodi\'{c}, Biserka and \v{S}kori\'{c}, Irena}, year = {2013}, pages = {1-14}, DOI = {10.1016/j.molstruc.2013.07.052}, keywords = {butadiene, chlorine, photochemistry, reaction mechanism, spectroscopy}, journal = {Journal of molecular structure}, doi = {10.1016/j.molstruc.2013.07.052}, volume = {1051}, issn = {0022-2860}, title = {Synthesis and photochemical transformations of new butadiene chromophores: the influence of the nature and position of chlorine substituent on the photoinduced behaviour}, keyword = {butadiene, chlorine, photochemistry, reaction mechanism, spectroscopy} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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  • CA Search (Chemical Abstracts)


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