Pregled bibliografske jedinice broj: 635004
Photoelectron spectroscopy of some chlorinated phosphate esters
Photoelectron spectroscopy of some chlorinated phosphate esters // Journal of electron spectroscopy and related phenomena, 189 (2013), 12-16 doi:10.1016/j.elspec.2013.06.002 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 635004 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Photoelectron spectroscopy of some chlorinated phosphate esters
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Journal of electron spectroscopy and related phenomena (0368-2048) 189
(2013);
12-16
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
phosphates; esters; photoelectron spectra; hyperconjugation
Sažetak
The electronic structures of ethylenephosphochloridate, 1, 2-phenylenephosphochloridate and 2, 2, 2-trichloro-1, 3, 2-benzodioxaphosphole have been studied by HeI/HeII photoelectron spectroscopy (UPS)and Green’s function calculations. Our results indicate the importance of hyperconjugative interactionsbetween the 5-membered ring and the fused aromatic ring. Some implications of our results for rates of ofnucleophilic substitution reactions on phosphorus are discussed
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
