Napredna pretraga

Pregled bibliografske jedinice broj: 633864

Thermal Behaviour and Structural Properties of Surfactant - Picrate Compounds: the effect of the ammonium headgroup number


Tomašić, Vlasta; Biliškov, Nikola; Mihelj, Tea; Štefanić, Zoran
Thermal Behaviour and Structural Properties of Surfactant - Picrate Compounds: the effect of the ammonium headgroup number // Thermochimica acta, 569 (2013), 25-35 doi:10.1016/j.tca.2013.06.041 (međunarodna recenzija, članak, znanstveni)


Naslov
Thermal Behaviour and Structural Properties of Surfactant - Picrate Compounds: the effect of the ammonium headgroup number

Autori
Tomašić, Vlasta ; Biliškov, Nikola ; Mihelj, Tea ; Štefanić, Zoran

Izvornik
Thermochimica acta (0040-6031) 569 (2013); 25-35

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Picric acid; cationic oligomeric surfactant; infrared spectroscopy; thermal analysis; crystal structure

Sažetak
Novel quaternary n-dodecyldimethylammonium picrates with two to four chains connected by an ethylene spacer at the ammonium headgroup level were synthesized. The effect of the headgroup number and the impact of picrate anion to their physicochemical properties was examined. Crystal structure of dimeric dipicrate is significantly different from bromide analogue. The dominant feature of this crystal packing is a layered structure with aromatic rings of picrate molecules, stacked via strong π•••π interactions and connected to the alkylammonium molecules with their nitro groups by C-H•••O hydrogen bonds. Weak NO2···HC hydrogen bonds further stabilize the structure. Higher degree of oligomerization leads to the less ordered solid phase and amorphous picrate structure. These amorphous structures result from widespread and disordered hydrogen bonding and rupture of π-π stacking in samples with more than two headgroups. Unlike corresponding bromides, picrate compounds show reversible phase transitions without thermal decomposition. Temperature-dependent infrared spectroscopy in the liquid phase detected adiabatic phase transitions.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982915-2949 - Površinski aktivne tvari, procesi u otopinama i na međupovršinama (Maja Dutour Sikirić, )
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Marija Luić, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati