engleski

MOF Materials from design to applications: Case studies of calcium- and magnesium-based carboxilates

In this contribution we present the study of Ca- and Mg-based MOF materials from rational design to application opportunities. In the case of Mg-benzene-1, 3, 5-tricarboxylate system we demonstrate how the solvent composition involved in the synthesis procedure plays the crucial role for the dimensionality of the final crystal structure. In the case of Ca-benzene-1, 4-dicarboxylate we present the detailed spectroscopic study of its structural dynamics upon heating and elucidated the mechanism of crystal-to-crystal transformation. Finally, we show the degradation study of Ca- and Mg-based aliphatic dicarboxylates (succinates, glutarates and pimelates) in body fluid conditions and discuss the possibility employ those materials for bio-applications.

MOFs; structural dynamic; rational design; bio-applications

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