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Structural investigation of aroylhydrazones derived from nicotinic acid hydrazide in solid state and in solution (CROSBI ID 596245)

Prilog sa skupa u zborniku | sažetak izlaganja sa skupa | domaća recenzija

Brođanac, Ivan ; Kontrec, Darko ; Miljanić, Snežana ; Galić, Nives Structural investigation of aroylhydrazones derived from nicotinic acid hydrazide in solid state and in solution // Knjiga sažetaka 23. Hrvatskog skupa kemičara i kemijskih inženjera / Hadžiev, Andrea ; Blažeković, Zdenko (ur.). Zagreb: Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI), 2013. str. 94-94

Podaci o odgovornosti

Brođanac, Ivan ; Kontrec, Darko ; Miljanić, Snežana ; Galić, Nives

engleski

Structural investigation of aroylhydrazones derived from nicotinic acid hydrazide in solid state and in solution

Structural forms of aroylhydrazones derived from nicotinic acid hydrazide have been studied in the solid state by FT-IR spectroscopy and in solution by NMR, UV-Vis and ATR spectroscopy. The studied compounds were N'-benzylidene-3-pyridinecarbohydrazide (1), N'-(2, 4-dihydroxyphenylmethylidene)-3-pyridinecarbohydrazide (2), N'-(5-chloro-2-hydroxyphenylmethylidene)-3-pyridinecarbohydrazide (3), and N'-(3, 5-dichloro-2-hydroxymethoxyphenylmethylidene)-3-pyridinecarbohydrazide (4). The compound 1 adopted the most stable ketoamine form (form I, –CO–NH–N=C–) in the solid state as well as in various organic solvents. In mixtures of organic solvents with water the UV-Vis and ATR spectra implied intermolecular hydrogen bonding of 1 with water molecules. The presence of both tautomeric forms I and II (form II, –COH=N¬–N=C–) was proposed for the solid substance and highly concentrated solutions of 2, whereas form I was detected as the predominant one in diluted solutions. For compounds 3 and 4 a coexistence of forms I and III (form III, –CO–NH–NH–C=C–CO–) was noticed in the solid state and in polar protic organic solvents. The conversion to form III was induced by increasing the water content in the solvent mixtures. This process was the most pronounced for compound 4. When exposed to daylight, an appearance of a new band was observed during time in the UV-Vis spectrum of 4 in organic solvent/water 1/1 mixtures which implied that tautomeric interconversion was most likely followed by E/Z isomerisation.

Aroylhydrazones ; Tautomerism ; Isomerisation ; Spectroscopy

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Podaci o prilogu

94-94.

2013.

objavljeno

Podaci o matičnoj publikaciji

Knjiga sažetaka 23. Hrvatskog skupa kemičara i kemijskih inženjera

Hadžiev, Andrea ; Blažeković, Zdenko

Zagreb: Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI)

978-953-6894-50-5

Podaci o skupu

23. HRVATSKI SKUP KEMIČARA I KEMIJSKIH INŽENJERA

poster

21.04.2013-24.04.2013

Osijek, Hrvatska

Povezanost rada

Kemija