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SYNTHESIS AND X-RAY STRUCTURAL ANALYSIS OF 1, 6-DISUBSTITUTED DIAMANTANES


Šekutor, Marina; Molčanov, Krešimir; Mlinarić-Majerski, Kata; Glaser, Robert
SYNTHESIS AND X-RAY STRUCTURAL ANALYSIS OF 1, 6-DISUBSTITUTED DIAMANTANES // 23. HRVATSKI SKUP KEMIČARA I KEMIJSKIH INŽENJERA
Osijek, 2013. str. 129-129 (poster, domaća recenzija, sažetak, znanstveni)


Naslov
SYNTHESIS AND X-RAY STRUCTURAL ANALYSIS OF 1, 6-DISUBSTITUTED DIAMANTANES

Autori
Šekutor, Marina ; Molčanov, Krešimir ; Mlinarić-Majerski, Kata ; Glaser, Robert

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
23. HRVATSKI SKUP KEMIČARA I KEMIJSKIH INŽENJERA / - Osijek, 2013, 129-129

Skup
23. HRVATSKI SKUP KEMIČARA I KEMIJSKIH INŽENJERA

Mjesto i datum
Osijek, Hrvatska, 21-24.04.2013

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
Rendgenska strukturna analiza; 1; 6-disubstituirani diadamantani
(X-ray structural analysis; 1; 6-disubstituted diadamananes)

Sažetak
Adamantane polycyclic compounds have recently found their use in studies of molecular recognition and self-assembly properties of cucurbit[n]uril macrocycles.[1] In these complexes the highly selective binding interactions with cationic species are driven by a combination of ion-dipole interactions, hydrogen bonds and the hydrophobic effect. We recently synthesized various 2, 6-diaminoadamantane salts [2] with the aim of studying their interactions with cucurbit[n]uril family of compounds and in the continuation of this research we turned our attention to diamantane.[3] Some 1, 6-disubstituted derivatives of diamantane are already known in the literature, [4] but we sought to synthesize the positively charged 1, 6-diamine salts such as 4 and 5 for further use in the binding studies. Herein we report the synthesis and crystal structure determination of a number of 1, 6- disubstituted diamantanes.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Kata Majerski, )

Ustanove
Institut "Ruđer Bošković", Zagreb