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Pregled bibliografske jedinice broj: 626805

Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions


Cindro, Nikola; Basarić, Nikola; Mlinarić-Majerski, Kata; Wan, Peter
Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions // 23. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka
Osijek, 2013. str. 158-158 (poster, domaća recenzija, sažetak, znanstveni)


CROSBI ID: 626805 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions

Autori
Cindro, Nikola ; Basarić, Nikola ; Mlinarić-Majerski, Kata ; Wan, Peter

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
23. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka / - Osijek, 2013, 158-158

Skup
Hrvatski skup kemičara i kemijskih inženjera (23 ; 2013)

Mjesto i datum
Osijek, Hrvatska, 21.-24.04.2013

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
fotokemija; homoadamantilni zwiterion; protoadamantilni zeiterion
(photochemistry; protoadamantyl zwitterion; homoadamantyl zwitterion)

Sažetak
Chemistry of nonspecific carbocations has been extensively investigated in the past decades. Within the scope of that research, a special attention was directed to adamantyl cation and its rearrangement reactions. Recently we reported a mild photochemical approach for the generation of adamantyl cations. Photo-dehydration reaction of phenol 1 delivers zwitterion 2, which rearranges to zwitterion 3 furnishing 2, 4-disubstituted adamantyl derivative 4. Herein we report on photochemical generation of zwitterions in an analogous photoreaction from 4-homoadamantyl- 5 and 4-protoadamantylphenol derivative 6. The cationic species formed in the photo-dehydration reaction were detected by transient spectroscopy. Reactivity of the zwitterionic intermediates was studied by preparative photo-solvolyses and laser flash photolysis.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
02.05/25 - Fotokemija policikličkih molekula: od istraživanja mehanizama reakcije do novih lijekova i medicinskih primjena (Basarić, Nikola, HRZZ ) ( POIROT)
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Majerski, Kata, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Kata Majerski (autor)

Avatar Url Nikola Basarić (autor)


Citiraj ovu publikaciju

Cindro, Nikola; Basarić, Nikola; Mlinarić-Majerski, Kata; Wan, Peter
Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions // 23. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka
Osijek, 2013. str. 158-158 (poster, domaća recenzija, sažetak, znanstveni)
Cindro, N., Basarić, N., Mlinarić-Majerski, K. & Wan, P. (2013) Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions. U: 23. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka.
@article{article, year = {2013}, pages = {158-158}, keywords = {fotokemija, homoadamantilni zwiterion, protoadamantilni zeiterion}, title = {Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions}, keyword = {fotokemija, homoadamantilni zwiterion, protoadamantilni zeiterion}, publisherplace = {Osijek, Hrvatska} }
@article{article, year = {2013}, pages = {158-158}, keywords = {photochemistry, protoadamantyl zwitterion, homoadamantyl zwitterion}, title = {Photochemical formation and reactivity of homoadamantyl : and protoadamantyl-zwitterions}, keyword = {photochemistry, protoadamantyl zwitterion, homoadamantyl zwitterion}, publisherplace = {Osijek, Hrvatska} }




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