Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 611904

The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study


Ren, Nan; Bronić, Josip; Bosnar, Sanja; Dutour Sikirić, Maja; Antonić Jelić, Tatjana; Mao, Jian-Jiang; Subotić, Boris
The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study // Crystengcomm, 15 (2013), 25; 5032-5044 doi:10.1039/C3CE26941H (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 611904 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study

Autori
Ren, Nan ; Bronić, Josip ; Bosnar, Sanja ; Dutour Sikirić, Maja ; Antonić Jelić, Tatjana ; Mao, Jian-Jiang ; Subotić, Boris

Izvornik
Crystengcomm (1466-8033) 15 (2013), 25; 5032-5044

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
crystallization ; transformation ; mechanism ; Zeolite ZSM-5 ; lamellar keatite ; hollow α-quartz

Sažetak
Crystallization/transformation processes in the reaction mixture: 4Na2O-0.1667Al2O3-100SiO2-4000H2O) seeded with 4 wt. % of 260-nm silicalite-1 seeds, at 170 oC were investigated by various experimental methods such as, X-ray diffraction (XRD), electron diffraction (ED), scanning-electron microscopy (SEM), transmission electron microscopy (TEM), particle size analysis (PSD), pH measurement, atomic absorption spectrometry (AAS) and dynamic light scattering (DLS). Analysis of the obtained results have shown that the crystallization/transformation takes place by a chain of processes: (i) dissolution of amorphous silica (used as silica source), and formation of 10 –50 nm precursor species (PSs), (ii) spending of the PSs for both the limited growth of zeolite ZSM-5 on the surfaces of silicalite-1 seed crystals and formation of worm-like particles (WLPs), (iii) formation of condensed aggregates (CAs) by aggregation/condensation of the WLPs ; a part of the composite particles, composed of silicalite-1 core and ZSM-5 shell are incorporated into CAs, (iv) nucleation of keatite followed by solution-mediated transformation of the condensed WLPs into lamellar keatite, (v) nucleation of -quartz followed by solution-mediated transformation of keatite into -quartz ; a part of nuclei of -quartz are formed at the surfaces of the core/shell silicalite-1/ZSM-5 composite species and another part of nuclei are formed in the vicinity of the dissolving keatite and (vi) dissolution of the silicalite-1 core and a major part of ZSM-5 “interlayer” of the composite particles (-quartz shell-ZSM-5 “interlayer”-silicalite-1 core) and formation of hollow -quartz particles with a thin ZSM-5 layer on the inner surfaces of the hollow -quartz particles. Occurrences of all the mentioned processes are rationally analyzed and explained on the basis of the existing and newly obtained knowledge.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982904-2953 - Studij utjecaja svojstava alumosilikatnih prekursora na njihove transformacije (Bronić, Josip, MZOS - )

Ustanove
Institut "Ruđer Bošković", Zagreb

Citiraj ovu publikaciju

Ren, Nan; Bronić, Josip; Bosnar, Sanja; Dutour Sikirić, Maja; Antonić Jelić, Tatjana; Mao, Jian-Jiang; Subotić, Boris
The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study // Crystengcomm, 15 (2013), 25; 5032-5044 doi:10.1039/C3CE26941H (međunarodna recenzija, članak, znanstveni)
Ren, N., Bronić, J., Bosnar, S., Dutour Sikirić, M., Antonić Jelić, T., Mao, J. & Subotić, B. (2013) The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study. Crystengcomm, 15 (25), 5032-5044 doi:10.1039/C3CE26941H.
@article{article, year = {2013}, pages = {5032-5044}, DOI = {10.1039/C3CE26941H}, keywords = {crystallization, transformation, mechanism, Zeolite ZSM-5, lamellar keatite, hollow α-quartz}, journal = {Crystengcomm}, doi = {10.1039/C3CE26941H}, volume = {15}, number = {25}, issn = {1466-8033}, title = {The relationship between sub-micrometer sized ZSM-5, slice-like (lamellar) keatite and hollow α-quartz particles : A phase transformation study}, keyword = {crystallization, transformation, mechanism, Zeolite ZSM-5, lamellar keatite, hollow α-quartz} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati





    Contrast
    Increase Font
    Decrease Font
    Dyslexic Font