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Pregled bibliografske jedinice broj: 610437

Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product


Lovrić, Milivoj; Jadreško, Dijana; Komorsky-Lovrić, Šebojka
Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product // Electrochimica acta, 90 (2013), 226-231 doi:10.1016/j.electacta.2012.11.101 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 610437 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product

Autori
Lovrić, Milivoj ; Jadreško, Dijana ; Komorsky-Lovrić, Šebojka

Izvornik
Electrochimica acta (0013-4686) 90 (2013); 226-231

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
theory; square-wave voltammetry; dimerization; kinetics of electrode reaction; the second order reaction mechanism

Sažetak
The influence of charge transfer kinetics and the rate of chemical reaction on square-wave voltammograms of electrode reaction followed by the dimerization of product is analyzed theoretically. The net peak potential is a linear function of the logarithm of reactant concentration if electrode reaction is reversible and the dimerization is either reversible, or totally irreversible. For the oxidation, the slopes of these relationships are -0.030 V and -0.022 V, respectively. Under the influence of electrode kinetics the linearity is lost. The relationship between net peak potential and the logarithm of frequency is linear either if electrode reaction is irreversible and the dimerization is reversible, or if electrode reaction is reversible and the dimerization is irreversible.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Poveznice na cjeloviti tekst rada:

doi www.sciencedirect.com ac.els-cdn.com dx.doi.org

Citiraj ovu publikaciju:

Lovrić, Milivoj; Jadreško, Dijana; Komorsky-Lovrić, Šebojka
Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product // Electrochimica acta, 90 (2013), 226-231 doi:10.1016/j.electacta.2012.11.101 (međunarodna recenzija, članak, znanstveni)
Lovrić, M., Jadreško, D. & Komorsky-Lovrić, Š. (2013) Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product. Electrochimica acta, 90, 226-231 doi:10.1016/j.electacta.2012.11.101.
@article{article, author = {Lovri\'{c}, Milivoj and Jadre\v{s}ko, Dijana and Komorsky-Lovri\'{c}, \v{S}ebojka}, year = {2013}, pages = {226-231}, DOI = {10.1016/j.electacta.2012.11.101}, keywords = {theory, square-wave voltammetry, dimerization, kinetics of electrode reaction, the second order reaction mechanism}, journal = {Electrochimica acta}, doi = {10.1016/j.electacta.2012.11.101}, volume = {90}, issn = {0013-4686}, title = {Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product}, keyword = {theory, square-wave voltammetry, dimerization, kinetics of electrode reaction, the second order reaction mechanism} }
@article{article, author = {Lovri\'{c}, Milivoj and Jadre\v{s}ko, Dijana and Komorsky-Lovri\'{c}, \v{S}ebojka}, year = {2013}, pages = {226-231}, DOI = {10.1016/j.electacta.2012.11.101}, keywords = {theory, square-wave voltammetry, dimerization, kinetics of electrode reaction, the second order reaction mechanism}, journal = {Electrochimica acta}, doi = {10.1016/j.electacta.2012.11.101}, volume = {90}, issn = {0013-4686}, title = {Theory of square-wave voltammetry of electrode reaction followed by the dimerization of product}, keyword = {theory, square-wave voltammetry, dimerization, kinetics of electrode reaction, the second order reaction mechanism} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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