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Pregled bibliografske jedinice broj: 609658

Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions


Lovrić, Milivoj; Komorsky-Lovrić, Šebojka
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions // Croatica chemica acta, 85 (2012), 4; 569-575 doi:10.5562/cca2126 (međunarodna recenzija, članak, znanstveni)


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Naslov
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions

Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka

Izvornik
Croatica chemica acta (0011-1643) 85 (2012), 4; 569-575

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Square-wave voltammetry; kinetics of electrode reaction; two-step electrode reaction; intermediate; standard rate constant.

Sažetak
An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of “kinetic burden” of potential inversion is described for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( POIROT)

Ustanove:
Institut "Ruđer Bošković", Zagreb

Poveznice na cjeloviti tekst rada:

doi Hrčak

Citiraj ovu publikaciju:

Lovrić, Milivoj; Komorsky-Lovrić, Šebojka
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions // Croatica chemica acta, 85 (2012), 4; 569-575 doi:10.5562/cca2126 (međunarodna recenzija, članak, znanstveni)
Lovrić, M. & Komorsky-Lovrić, Š. (2012) Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions. Croatica chemica acta, 85 (4), 569-575 doi:10.5562/cca2126.
@article{article, author = {Lovri\'{c}, Milivoj and Komorsky-Lovri\'{c}, \v{S}ebojka}, year = {2012}, pages = {569-575}, DOI = {10.5562/cca2126}, keywords = {Square-wave voltammetry, kinetics of electrode reaction, two-step electrode reaction, intermediate, standard rate constant.}, journal = {Croatica chemica acta}, doi = {10.5562/cca2126}, volume = {85}, number = {4}, issn = {0011-1643}, title = {Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions}, keyword = {Square-wave voltammetry, kinetics of electrode reaction, two-step electrode reaction, intermediate, standard rate constant.} }
@article{article, author = {Lovri\'{c}, Milivoj and Komorsky-Lovri\'{c}, \v{S}ebojka}, year = {2012}, pages = {569-575}, DOI = {10.5562/cca2126}, keywords = {Square-wave voltammetry, kinetics of electrode reaction, two-step electrode reaction, intermediate, standard rate constant.}, journal = {Croatica chemica acta}, doi = {10.5562/cca2126}, volume = {85}, number = {4}, issn = {0011-1643}, title = {Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions}, keyword = {Square-wave voltammetry, kinetics of electrode reaction, two-step electrode reaction, intermediate, standard rate constant.} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati:





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