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Pregled bibliografske jedinice broj: 607105

Synthesis and tautomerism of two benzothiazolyl azo dyes


Racane, Livio; Cerić, Helena; Tralić-Kulenović, Vesna
Synthesis and tautomerism of two benzothiazolyl azo dyes // Book of Proceedings of the 6th International Textile, Clothing & Design Conference / Dragčević, Zvonko (ur.).
Zagreb: TTF-Sveučilište u Zagrebu, 2012. str. 278-282 (poster, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)


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Naslov
Synthesis and tautomerism of two benzothiazolyl azo dyes

Autori
Racane, Livio ; Cerić, Helena ; Tralić-Kulenović, Vesna

Vrsta, podvrsta i kategorija rada
Radovi u zbornicima skupova, cjeloviti rad (in extenso), znanstveni

Izvornik
Book of Proceedings of the 6th International Textile, Clothing & Design Conference / Dragčević, Zvonko - Zagreb : TTF-Sveučilište u Zagrebu, 2012, 278-282

Skup
6th International Textile, Clothing & Design Conference

Mjesto i datum
Dubrovnik, Hrvatska, 07-10.10.2012

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
azo dyes; benzothiazole; NMR spectroscopy; tautomerism

Sažetak
Azo dyes with hydroxy group in conjugation to the azo chromophore exhibit azo-hydrazone tautomerism, and the existence of this proton transfer between oxygen and nitrogen atoms is quite interesting from the theoretical and practical aspects. The position of tautomeric equilibrium affects the basic properties of azo dyes, such as color, tone and photostability, as well as technical properties of different tautomers. On the other hand, replacement of aromatic diazo component with heteroaromatic is interesting from the toxicological point of view because some of aromatic azo dyes can undergo natural reductive cleavage of azo group to potentially carcinogenic amines. We report the efficient synthesis of 6-[(2-hydroxy-1-naphthyl)diazenyl]-2-methylbenzothiazole and investigate tautomerism of two benzothiazolyl azo dyes using C–2 carbon chemical shifts. For unequivocal determination of C–2 chemical shift a complete assignment of signals in 1H and 13C NMR spectra was established by 2D NMR techniques. These azo dyes exist as a rapidly exchanging mixture of azo and hydrazone forms and the tautomeric equilibrium are slightly shifted towards hydrazone forms.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Tekstilna tehnologija



POVEZANOST RADA


Projekti:
117-0000000-3283 - Istraživanje novih višenamjenskih bojila i optičkih bjelila (Racane, Livio, MZOS ) ( POIROT)

Ustanove:
Tekstilno-tehnološki fakultet, Zagreb

Profili:

Avatar Url Vesna Tralić-Kulenović (autor)

Avatar Url Livio Racane (autor)

Citiraj ovu publikaciju

Racane, Livio; Cerić, Helena; Tralić-Kulenović, Vesna
Synthesis and tautomerism of two benzothiazolyl azo dyes // Book of Proceedings of the 6th International Textile, Clothing & Design Conference / Dragčević, Zvonko (ur.).
Zagreb: TTF-Sveučilište u Zagrebu, 2012. str. 278-282 (poster, međunarodna recenzija, cjeloviti rad (in extenso), znanstveni)
Racane, L., Cerić, H. & Tralić-Kulenović, V. (2012) Synthesis and tautomerism of two benzothiazolyl azo dyes. U: Dragčević, Z. (ur.)Book of Proceedings of the 6th International Textile, Clothing & Design Conference.
@article{article, editor = {Drag\v{c}evi\'{c}, Z.}, year = {2012}, pages = {278-282}, keywords = {azo dyes, benzothiazole, NMR spectroscopy, tautomerism}, title = {Synthesis and tautomerism of two benzothiazolyl azo dyes}, keyword = {azo dyes, benzothiazole, NMR spectroscopy, tautomerism}, publisher = {TTF-Sveu\v{c}ili\v{s}te u Zagrebu}, publisherplace = {Dubrovnik, Hrvatska} }
@article{article, editor = {Drag\v{c}evi\'{c}, Z.}, year = {2012}, pages = {278-282}, keywords = {azo dyes, benzothiazole, NMR spectroscopy, tautomerism}, title = {Synthesis and tautomerism of two benzothiazolyl azo dyes}, keyword = {azo dyes, benzothiazole, NMR spectroscopy, tautomerism}, publisher = {TTF-Sveu\v{c}ili\v{s}te u Zagrebu}, publisherplace = {Dubrovnik, Hrvatska} }




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