An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines (CROSBI ID 185423)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Vinter, Adrijana ; Avdagić, Amir ; Štimac, Vlado ; Palej, Ivana ; Čikoš, Ana ; Šunjić, Vitomir ; Alihodžić, Sulejman
engleski
An Expeditious Method for the Preparation of 2- Hydroxy-1, 4-dioxane and Its Use in Reductive Alkylation of Amines
Selective oxidation of diethylene glycol by a ruthenium(VIII) species, obtained in situ from ruthenium(III) chloride-sodium periodate in the presence of a catalytic quantity of water, affords a monoaldehyde in the form of the internal acetal 2-hydroxy-1, 4-dioxane. This compound was used in reductive alkylations of selected primary and secondary amines, demonstrating its utility in the preparation of target structures with the 2-(2- hydroxyethoxy)ethylamino unit.
diethylene glycol - oxidations - reductive alkylations - 2-hydroxy-1; 4-dioxane - ruthenium(VIII) catalysis
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano