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Mechanochemical synthesis of guanidine - Zinc and Cadmium metal-organic frameworks


Štrukil, Vjekoslav; Fábián, L.; Reid, D. G.; Duer, M. J.; Jackson, G. J.; Eckert-Maksić, Mirjana; Friščić, Tomislav; Margetić, Davor
Mechanochemical synthesis of guanidine - Zinc and Cadmium metal-organic frameworks // Book of abstracts Challenges in Organic Chemistry and Chemical Biology (ISACS7)
Edinburgh: Royal Society of Chemistry, 2012. (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
Mechanochemical synthesis of guanidine - Zinc and Cadmium metal-organic frameworks

Autori
Štrukil, Vjekoslav ; Fábián, L. ; Reid, D. G. ; Duer, M. J. ; Jackson, G. J. ; Eckert-Maksić, Mirjana ; Friščić, Tomislav ; Margetić, Davor

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of abstracts Challenges in Organic Chemistry and Chemical Biology (ISACS7) / - Edinburgh : Royal Society of Chemistry, 2012

Skup
Challenges in Organic Chemistry and Chemical Biology (ISACS7)

Mjesto i datum
Edinburgh, UK, 12-15.06.2012

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Mechanochemistry

Sažetak
Metal-organic frameworks (MOFs) are a class of crystalline materials that consist of metal ions and organic ligands linked together by coordination bonds. Because of their porosity and the possibility of combining large surface areas with pore characteristics that can be tailored, these materials show great promise for a wide range of applications. Employment of mechanochemical synthesis is novel way of the manipulation of the dimensionality of MOFs.1, 2 Results of mechanochemical synthesis of guanidine (cng) - zinc and cadmium complexes were presented in which guanidine acts as a heteroditopic ligand.3 It was found that mechanochemical synthesis via neat or liquid-assisted grinding (LAG) methodologies offers a simple, rapid and clean way to control the stioichiometry and dimensionality of MOFs (Figure 1). A complete implementation of the “solvent-free synthesis paradigm” in an environmentally-friendly MOFs synthesis was achieved via neat grinding, quantitative yields and product analysis by PXRD and solid state NMR.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-2920 - Organski i bioorganski procesi u osnovnom i elektronski pobuđenim stanjima (Mirjana Maksić, )
098-0982933-3218 - 'Host-guest' međudjelovanja u policikličkim sustavima (Davor Margetić, )

Ustanove
Institut "Ruđer Bošković", Zagreb