Structural properties of precipitates formed by hydrolysis of Fe3+ ions in aqueous solutions containing NO3- and Cl- ions (CROSBI ID 183854)
Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija
Podaci o odgovornosti
Gotić, Marijan ; Popović, Stanko ; Ljubešić, Nikola ; Musić, Svetozar
engleski
Structural properties of precipitates formed by hydrolysis of Fe3+ ions in aqueous solutions containing NO3- and Cl- ions
The structural properties of precipitates formed by hydrolysis of Fe3+ ions in aqueous solutions, containing N03-and Cl- ions, were investigated. The reactions of hydrolysis were performed in glass autoclaves at 120 °C. X-ray diffraction showed that α-FeOOH and α-Fe2O3 were present in hydrolytical products formed in solutions containing N03-ions, while β-FeOOH and α-Fe2O3 were typical hydrolytical products in solutions containing Cl- ions. In the mixed Fe(N03)3+FeCl3 solutions, the phase composition of the hydrolytical products was determined by the concentration of the dominant Fe(III)-salt. Fourier transform infrared spectroscopy and Mössbauer spectroscopy were also used for the structural characterizations of the hydrolytical products. Transmission electron microscopy showed a diversity of shapes of the particles, which depended strongly on the experimental conditions. All types of particle, observed by transmission electron microscopy, were interpreted.
α-FeOOH ; α-Fe2O3 ; β-FeOOH ; Iron oxides precipitates ; Aqueous solutions ; Chloride ions ; Nitrate ions ; Hydrolysis ;
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
nije evidentirano
Podaci o izdanju
29 (9)
1994.
2474-2480
objavljeno
0022-2461
1573-4803
10.1007/BF00363442