Theory of square-wave voltammetry of two electron reduction with the adsorption of intermediate (CROSBI ID 182998)
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Podaci o odgovornosti
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
engleski
Theory of square-wave voltammetry of two electron reduction with the adsorption of intermediate
Thermodynamically unstable intermediate of fast and reversible two electron electrode reaction can be stabilized by the adsorption to the electrode surface. In square-wave voltammetry of this reaction mechanism the split response may appear if the electrode surface is not completely covered by the adsorbed intermediate. The dependence of the difference between the net peak potentials of the prepeak and postpeak on the square-wave frequency is analysed theoretically. This relationship can be used for the estimation of adsorption constant.
Square-wave voltammetry ; two electron electrode reaction ; adsorption of intermediate ; theory of EE mechanism
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Podaci o izdanju
2012
2012.
1-7
objavljeno
2090-3529
2090-3537
10.1155/2012/596268
Povezanost rada
Kemija