engleski

Synthesis of Functionalized Polynorbornanes Employing 2, 5-Bis(trifluoromethyl)-1, 3, 4-oxadiazole

Cycloaddition reaction of 2, 5-bis(trifluoromethyl)-1, 3, 4-oxadiazole with strained olefinic bonds of norbornenes was used to synthetise functionalized polynorbornanes. This simple, one step procedure was more effective when reaction was carried out by classical heating, in comparison to microwave assisted reactions. Various functional groups were stable in the reaction conditions (ester, imide, phthalimide, piperidyl, carboxylic acid), while anhydride, NBoc or TMS functionalities do not withstand reaction conditions.

Microwave; synthesis; cycloadditions

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