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Pregled bibliografske jedinice broj: 529201

The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O


Bilinski, Halka; Matković, Boris; Mažuranić, Karmen; Balić-Žunić, Tonči
The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O // Journal of the American Ceramic Society, 67 (1984), 4; 266-269 doi:10.1111/j.1151-2916.1984.tb18844.x (međunarodna recenzija, članak, znanstveni)


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Naslov
The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O

Autori
Bilinski, Halka ; Matković, Boris ; Mažuranić, Karmen ; Balić-Žunić, Tonči

Izvornik
Journal of the American Ceramic Society (0002-7820) 67 (1984), 4; 266-269

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
X-ray diffraction analysis ; Magnesium Oxychloride Phases

Sažetak
The reactions leading to the formation of crystalline Mg3(OH)5Cl·4H2O (phase 5), Mg2(OH)3, Cl·4H2O (phase 3), and Mg(OH)2 are compared for the systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O. The crystalline phases were determined by X-ray diffraction analysis. The concentration of the total magnesium and chloride in the solution and the pH of the solution determine the reaction product(s) in both systems. The influence of MgO reactivity and the molar ratio of reactants on the formation and stability of reaction products is discussed and the mechanism of the formation of phases 3 and 5 is explained. In the system MgO-MgCl2-H2O, MgO serves only to increase the concentration of total magnesium and the pH of the MgCl2 solution.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Ustanove:
Institut "Ruđer Bošković", Zagreb,
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Citiraj ovu publikaciju

Bilinski, Halka; Matković, Boris; Mažuranić, Karmen; Balić-Žunić, Tonči
The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O // Journal of the American Ceramic Society, 67 (1984), 4; 266-269 doi:10.1111/j.1151-2916.1984.tb18844.x (međunarodna recenzija, članak, znanstveni)
Bilinski, H., Matković, B., Mažuranić, K. & Balić-Žunić, T. (1984) The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O. Journal of the American Ceramic Society, 67 (4), 266-269 doi:10.1111/j.1151-2916.1984.tb18844.x.
@article{article, year = {1984}, pages = {266-269}, DOI = {10.1111/j.1151-2916.1984.tb18844.x}, keywords = {X-ray diffraction analysis, Magnesium Oxychloride Phases}, journal = {Journal of the American Ceramic Society}, doi = {10.1111/j.1151-2916.1984.tb18844.x}, volume = {67}, number = {4}, issn = {0002-7820}, title = {The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O}, keyword = {X-ray diffraction analysis, Magnesium Oxychloride Phases} }
@article{article, year = {1984}, pages = {266-269}, DOI = {10.1111/j.1151-2916.1984.tb18844.x}, keywords = {X-ray diffraction analysis, Magnesium Oxychloride Phases}, journal = {Journal of the American Ceramic Society}, doi = {10.1111/j.1151-2916.1984.tb18844.x}, volume = {67}, number = {4}, issn = {0002-7820}, title = {The Formation of Magnesium Oxychloride Phases in the Systems MgO-MgCl2-H2O and NaOH-MgCl2-H2O}, keyword = {X-ray diffraction analysis, Magnesium Oxychloride Phases} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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