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Green Synthesis, X-ray and Spectroscopic Analysis of 2, 6–di(p–tolyl)–pyran–4–one


Tranfić, Marina; Ilčić, Tea; Makovec, Sanja; Cetina, Mario; Jukić, Marijana
Green Synthesis, X-ray and Spectroscopic Analysis of 2, 6–di(p–tolyl)–pyran–4–one // The 13th European Symposium on Organic Reactivity - Book of Abstracts / Burk, Peeter (ur.).
Tartu, Estonija, 2011. (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
Green Synthesis, X-ray and Spectroscopic Analysis of 2, 6–di(p–tolyl)–pyran–4–one

Autori
Tranfić, Marina ; Ilčić, Tea ; Makovec, Sanja ; Cetina, Mario ; Jukić, Marijana

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
The 13th European Symposium on Organic Reactivity - Book of Abstracts / Burk, Peeter - Tartu, Estonija, 2011

ISBN
978-9985-4-0670-0

Skup
The 13th European Symposium on Organic Reactivity

Mjesto i datum
Tartu, Estonija, 11-16.09.2011

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Green chemistry; pyrone; microwave activation; X–ray structural analysis; UV/Vis spectroscopy; fluorescence

Sažetak
Pyrones are the fundamental moieties of a number of naturally occurring compounds as well as some synthetic compounds that show a variety of biological activities. They are the core of coumarin dyes and possess interesting optical properties. Additionally, pyrones are very useful synthetic reagents. Our previous work was focused on systematic research of synthesis and analysis of heterocyclic bioactive molecules. As a part of that research, our ongoing research includes „green” synthesis and structural characterization of a new derivative of pyrone which is assumed to be of biological and pharmacological importance. Synthesis via activation by microwave radiation showed advantages compared to classical organic synthesis, since it enables significant acceleration of organic reactions and gives greater efficiency in moderate reaction conditions. The structure of pyrone derivative, that was synthesized both by classical (18 h) and by microwave activation (30 min), was confirmed by 1H–NMR, 13C–NMR and IR spectroscopy. Furthermore, its crystal structure was determined and its behavior in solutions was examined. Various effects of media, such as temperature, pH and solvent used, on its ground and excited electron states, were investigated and are commented.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
058-0582261-2253 - Ekološke priprave i elektrokemijska karakterizacija biološki aktivnih spojeva (Marijana Jukić, )
119-1193079-3069 - Novi organski i koordinacijski spojevi - sinteza i suodnos struktura-svojstvo (Branko Kaitner, )

Ustanove
Prehrambeno-biotehnološki fakultet, Zagreb