Stabilisation of tetrabromo- and tetrachlorosemiquinone (bromanil and chloranil) anion radicals in crystals (CROSBI ID 171879)
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Molčanov, Krešimir ; Kojić-Prodić, Biserka ; Babić, Darko ; Žilić, Dijana ; Rakvin, Boris
engleski
Stabilisation of tetrabromo- and tetrachlorosemiquinone (bromanil and chloranil) anion radicals in crystals
Crystal structures of alkali salts of tetrahaolgenosemiquinone anion radical acetone solvates and their solvent-free salts are determined. p-Semiquinone anion radical reveals enhanced aromaticity of the ring compared to the quinone. A pair of π-stacked radical anion (p-semiquinone) rings occurs in crystal structures of potassium and rubidium salts of tetrachlorosemiquinone anion acetone solvates and their potassium tetrabromo analogue. The ring centroid separation distances are about 3.2 Å and carbon-carbon contacts between the contiguous rings are 0.3 Å shorter than the sum of van der Waals radii. The spin-coupling of the two unpaired electrons between the two anion radical rings (forming a stacked dimer) correlates with diamagnetic property of crystals. Magnetic properties of alkali salts of tetrahaolgenosemiquinone anion radical acetone solvates were examined by electron paramagnetic resonance spectroscopy.
semiquinone radical anion; tetrachlorosemiquinone; chloranil; tetrabromosemiquinone; bromanil; crystal structures; π•••π stacking; radical anion dimers; antiferromagnetic coupling; magnetic properties; EPR
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