Pretražite po imenu i prezimenu autora, mentora, urednika, prevoditelja

Napredna pretraga

Pregled bibliografske jedinice broj: 504685

Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide


Cindro, Nikola; Horvat, Margareta; Mlinarić-Majerski, Kata; Griesbeck, Axel G.; Basarić, Nikola
Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide // Beilstein journal of organic chemistry, 7 (2011), 270-277 doi:10.3762/bjoc.7.36 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 504685 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide

Autori
Cindro, Nikola ; Horvat, Margareta ; Mlinarić-Majerski, Kata ; Griesbeck, Axel G. ; Basarić, Nikola

Izvornik
Beilstein journal of organic chemistry (1860-5397) 7 (2011); 270-277

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
homoadamantanes ; photoinduced H-abstraction ; phthalimides

Sažetak
N-(4-homoadamantyl)phthalimide (5) on excitation and population of the triplet excited state underwent intramolecular H-abstractions and gave products 6 and 7. The major product, exo-alcohol 6 was a result of the regioselective δ H-abstraction and the stereoselective cyclization of the 1, 5-biradical. Minor products 7 were formed by photoinduced γ H-abstractions, followed by ring closure to azetidinols and ring enlargement to azepinediones. The observed selectivity to exo-alcohol 6 was explained by the conformation of 5 and the best orientation and the availability of the δ-H for the abstraction.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
02.05/25
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Kata Majerski, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Nikola Basarić (autor)

Avatar Url Kata Majerski (autor)

Avatar Url Nikola Cindro (autor)

Avatar Url Margareta Sohora (autor)

Citiraj ovu publikaciju

Cindro, Nikola; Horvat, Margareta; Mlinarić-Majerski, Kata; Griesbeck, Axel G.; Basarić, Nikola
Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide // Beilstein journal of organic chemistry, 7 (2011), 270-277 doi:10.3762/bjoc.7.36 (međunarodna recenzija, članak, znanstveni)
Cindro, N., Horvat, M., Mlinarić-Majerski, K., Griesbeck, A. & Basarić, N. (2011) Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide. Beilstein journal of organic chemistry, 7, 270-277 doi:10.3762/bjoc.7.36.
@article{article, year = {2011}, pages = {270-277}, DOI = {10.3762/bjoc.7.36}, keywords = {homoadamantanes, photoinduced H-abstraction, phthalimides}, journal = {Beilstein journal of organic chemistry}, doi = {10.3762/bjoc.7.36}, volume = {7}, issn = {1860-5397}, title = {Photoinduced homolytic C–H activation in N-(4-homoadamantyl)phthalimide}, keyword = {homoadamantanes, photoinduced H-abstraction, phthalimides} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Citati