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Crystal structures of modified PNA analogues and of cationic diimine Pd(II)-alkyl complex


Yennawar, Hemant P.; Kirin, Srećko I.; Borkar, Sachin; Williams, Mary Beth; Sen, Ayusman
Crystal structures of modified PNA analogues and of cationic diimine Pd(II)-alkyl complex // Abstracts of the Congress of the International Union of Crystallography ; u: Acta Cryst. A64 (2008) / - (ur.).
-, 2008. str. C413-C413 (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
Crystal structures of modified PNA analogues and of cationic diimine Pd(II)-alkyl complex

Autori
Yennawar, Hemant P. ; Kirin, Srećko I. ; Borkar, Sachin ; Williams, Mary Beth ; Sen, Ayusman

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Abstracts of the Congress of the International Union of Crystallography ; u: Acta Cryst. A64 (2008) / - , 2008, C413-C413

Skup
XXI Congress of the International Union of Crystallography

Mjesto i datum
Osaka, Japan, 23.-31.08.2008

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
PNA analogues; synthesis of copolymers; crystal structure

Sažetak
Nature provides the best inspiration for development of new materials. Inorganic nucleic acid derivatives and structural mimics are receiving increased attention in recent years. We present four structures of Cu(II) complexes with amino acid substituted Di(2pyridyl) amine ligands which can serve as inorganic analogs of nucleic acids. Two of these structures have interesting intermolecular interactions and will be presented in the poster. In addition, we also present the structure of a monomer synthesized by reacting Pd(II) diimine complex with methyl methacrylate. This complex has been used to synthesize poly(alkene-block-alkene/carbon monoxide) copolymers. Late transition metal based systems have attracted attention recently, due to their lower oxophilicity and relatively high functionality tolerance. Catalytic synthesis of such copolymers is of immense interest as they may have new desirable properties.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982904-2946 - Višenuklearni metalni sustavi: sinteza i svojstva (Berislav Perić, )

Ustanove
Institut "Ruđer Bošković", Zagreb

Autor s matičnim brojem:
Srećko Kirin, (192540)

Časopis indeksira:


  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)