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A Mechanochemical Approach Towards Solvent-Free Synthesis


Štrukil, Vjekoslav; Fábián, Lászlo; Reid, David G.; Duer, Melinda J.; Eckert-Maksić, Mirjana; Friščić, Tomislav
A Mechanochemical Approach Towards Solvent-Free Synthesis // Symposium on Mechanochemistry and Solvent-free Synthesis / James ; Stuart (ur.).
Belfast: Queen’s University of Belfast, 2009. str. 32-32 (poster, međunarodna recenzija, sažetak, znanstveni)


Naslov
A Mechanochemical Approach Towards Solvent-Free Synthesis

Autori
Štrukil, Vjekoslav ; Fábián, Lászlo ; Reid, David G. ; Duer, Melinda J. ; Eckert-Maksić, Mirjana ; Friščić, Tomislav

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Symposium on Mechanochemistry and Solvent-free Synthesis / James ; Stuart - Belfast : Queen’s University of Belfast, 2009, 32-32

Skup
Symposium on Mechanochemistry and Solvent-free Synthesis

Mjesto i datum
Belfast, UK, 06-07. 11. 2009.

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Mechanosynthesis; metal-organic polymers

Sažetak
Growing problems of pollution and shrinking energy resources have imposed the necessity to devise chemical processes that are environmentally-friendly and energy-efficient, while still economically accessible. In the development of such „green chemistry“, we have recognised chemical synthesis induced by mechanical force, or mechanochemistry, as a method of choice. We are intrigued by the possibility that the recently developed and highly efficient mechanochemical methods, such as liquid-assisted grinding can be combined with solid-state analytical methods (structure solution from X-ray powder diffraction data and solid-state NMR) to achieve a fully „solvent-free research laboratory“: a complete implementation of the solvent-free paradigm in chemical research. In this contribution, we will describe our first results in that direction, achieved in the field of metal-organic synthesis. We demonstrate how mechanosynthesis allows the screening for different compositions of metal-organic polymers of zinc and cadmium with a heteroditopic ligand cyanoguanidine, followed by structural characterisation through solid- state NMR and PXRD.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

Napomena
Nagrada za najbolji poster



POVEZANOST RADA


Projekt / tema
098-0982933-2920 - Organski i bioorganski procesi u osnovnom i elektronski pobuđenim stanjima (Mirjana Maksić, )

Ustanove
Institut "Ruđer Bošković", Zagreb