engleski

Synthesis, Characterization and Electrochemical Behaviour of Co(II) and Co(III) Complexes with Salen-type Ligand

Co(II) and Co(III) complexes with salen-type ligands have been widely studied as Vit. B12 models, O2 carriers or activators, oxidation catalysts and supramolecular building blocks1. We have synthesized and characterized a new series of inorganic and organometallic Co(III) Schiff base complexes, containing the tetradentate ligand (3Ac-Tyr)2en, derived from the condensation of 3-acetyltyrosine with ethylenediamine (Fig. 1, a), amenable to incorporation into peptide fragments.

Co(II) and Co(III) complexes ; salen-type ligands

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