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Synthesis and phototransformations of novel styryl-substituted furobenzobicyclo[3.2.1]octadiene derivatives (CROSBI ID 164955)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Kikaš, Ilijana ; Škorić, Irena ; Marinić, Željko ; Šindler-Kulyk, Marija Synthesis and phototransformations of novel styryl-substituted furobenzobicyclo[3.2.1]octadiene derivatives // Tetrahedron, 66 (2010), 48; 9405-9414. doi: 10.1016/j.tet.2010.09.093

Podaci o odgovornosti

Kikaš, Ilijana ; Škorić, Irena ; Marinić, Željko ; Šindler-Kulyk, Marija

engleski

Synthesis and phototransformations of novel styryl-substituted furobenzobicyclo[3.2.1]octadiene derivatives

Novel cis- and trans-(o-H/Me/vinyl) substituted styryl furo-benzobicyclo[3.2.1]octadiene derivatives (7a, b, 8) were prepared and transformed to the novel naphthofuran derivatives of benzobicyclo[3.2.1]octadiene (6a, b) and novel phenanthrene-benzobicyclo[3.2.1]octadiene derivative (11) by photochemical electrocyclic ring closure in the presence of iodine and by intramolecular photoinduced [4+2] cycloaddition, respectively. These novel annelated bicyclo[3.2.1]octadiene derivatives (6a, b, 11) are especially interesting for their rigid methanobridged junction of two aromatic units at defined geometrical arrangement and thereby as potentials for molecular clips.

electrocyclization ; furan ; intramolecular cycloaddition ; photochemistry ; synthesis

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Podaci o izdanju

66 (48)

2010.

9405-9414

objavljeno

0040-4020

1464-5416

10.1016/j.tet.2010.09.093

Povezanost rada

Kemija

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