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Ion- and Liquid-Assisted Grinding: Improved Mechanochemical Synthesis of Metal–Organic Frameworks Reveals Salt Inclusion and Anion Templating

Just a pinch of salt: Small amounts of salts accelerate and direct the mechanochemical construction of metal-organic frameworks (MOFs) from a metal oxide (see scheme ; ILAG= ion- and liquid-assisted grinding). The resulting rapid and room-temperature synthesis demonstrates the ability to control mechanosynthesis of metal-organic compounds by templating, as well as the ability to use mechanochemistry to include ionic guests within neutral MOFs.

ions ; mechanochemistry ; metal-organic frameworks ; solid-state reactions ; sustainable chemistry

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