Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex (CROSBI ID 163760)
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Kandaiah, Sakthivel ; Halasz, Ivan ; Dinnebier, Robert E. ; Jansen Martin
engleski
Electrochemical synthesis and crystal structure of a penta-coordinated silver(II) macrocyclic complex
We present the electrochemical synthesis by galvanostatic electro-oxidation method and single crystal structure determination of a complex of silver(II) with a macrocyclic N donor ligand crystallized with hexafluorophosphate anions. The crystal structure analysis showed a penta-coordinated environment of silver(II) and displacement of the metal centre from the rectangular planar configuration of the macrocyclic N donor which is due to axial coordination by a solvent acetonitrile molecule. Both PF6- anions were modelled with two-fold disorder.
Silver; Higher oxidation state; Tetramethyltetraazacyclotetradecane; Electrochemical synthesis; Solvent coordination; hexafluorophosphate
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