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Behavior of Al-Ga Alloy on the Negative Side of the Open - circuit Potential in Sodium Chloride Solution


Višekruna, Antonija; Radošević, Jagoda; Slavica Matešić, Sanja; Krnić, Nikša
Behavior of Al-Ga Alloy on the Negative Side of the Open - circuit Potential in Sodium Chloride Solution // ECS Transactions : Oxide Films / Marcus, P. ; Fujimoto, S. ; Terryn, H. (ur.).
New Jersey: The Electrochemical Society, 2010. str. 105-115


Naslov
Behavior of Al-Ga Alloy on the Negative Side of the Open - circuit Potential in Sodium Chloride Solution

Autori
Višekruna, Antonija ; Radošević, Jagoda ; Slavica Matešić, Sanja ; Krnić, Nikša

Vrsta, podvrsta i kategorija rada
Poglavlja u knjigama, znanstveni

Knjiga
ECS Transactions : Oxide Films

Urednik/ci
Marcus, P. ; Fujimoto, S. ; Terryn, H.

Izdavač
The Electrochemical Society

Grad
New Jersey

Godina
2010

Raspon stranica
105-115

ISBN
978-1-56677-814-5

Ključne riječi
Aluminium activation, Al-Ga alloy, cathodic polarization, hydration potential

Sažetak
The influence of the addition of small quantities gallium to high-purity aluminium on its electrochemical behaviour at high cathodic potentials (up to -2.0 V vs. SCE) was investigated using the potentiostatic pulse method. After cathodic polarization, anodic current was traced vs. time in order to determine the quantity of charge necessary for oxidation of substances formed. Anodic current responses to the return to the EOCP were also recorded in the period of 1 s. Time responses of the cathodic and anodic current were analyzed. The range of low and high cathodic potentials (LCP, HCP) was defined for all the samples. It has been established that the oxide film retains its properties in the LCP range, while in the HCP range cathodic breakdown and hydration of the oxide take place. Electrochemical methods complemented by SEM and EDAX analysis before and after the cathode pulse of -1.9 V vs. SCE.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo, Strojarstvo

Napomena
216th ECS Meeting ; ISSN 1938-5862 ; Sažetak rada je objavljen u Knjizi sažetaka.



POVEZANOST RADA


Projekt / tema
023-1252973-2243 - Elektrokemijski procesi na granici faza i fizikalna svojstva površina-ELGRAFAIII (Jagoda Radošević, )

Ustanove
Fakultet elektrotehnike, strojarstva i brodogradnje, Split