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Anion recognition through hydrogen bonding by adamantane-dipyrromethane receptors


Alešković, Marija; Basarić, Nikola; Mlinarić-Majerski, Kata; Molčanov, Krešimir; Kojić-Prodić, Biserka; Kesharwani, Manoj K.; Ganguly, Bishwajit
Anion recognition through hydrogen bonding by adamantane-dipyrromethane receptors // Tetrahedron, 66 (2010), 9; 1689-1698 doi:10.1016/j.tet.2010.01.018 (međunarodna recenzija, članak, znanstveni)


Naslov
Anion recognition through hydrogen bonding by adamantane-dipyrromethane receptors

Autori
Alešković, Marija ; Basarić, Nikola ; Mlinarić-Majerski, Kata ; Molčanov, Krešimir ; Kojić-Prodić, Biserka ; Kesharwani, Manoj K. ; Ganguly, Bishwajit

Izvornik
Tetrahedron (0040-4020) 66 (2010), 9; 1689-1698

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Anion receptors ; pyrrole ; DFT calculations

Sažetak
Adamantane-dipyrromethane (AdD) receptors [di(pyrrole-2-yl)methyladamantane (1), 2, 2-di(pyrrole-2-yl)adamantane (2), 1, 3-bis[di(pyrrole-2-yl)methyl]adamantane (3), 2, 2, 6, 6-tetra(pyrrole-2-yl)adamantane (4)] form complexes with F-, Cl-, Br-, AcO-, NO3-, HSO4-, and H2PO4-. The association constants of the complexes were determined by 1H NMR titrations, whereas the geometries of complexes 1•F- (2:1), 2•F- (2:1), 2•Cl- (2:1), 2•AcO- (2:1), and 4•F- (1:1) were determined by X-ray structural analysis. The most stable complexes are of 2:1 stoichiometry with F- and AcO-. The stability constants are in accordance with the anion basicity and the ability of AdD receptors to place the hydrogen bonding donor groups in a tetrahedral fashion around anions. The binding energies of the complexes between receptors 1-4 and F- anion are calculated using quantum chemical methods. The calculated results show that the solvent polarity is important for the complexation of fluoride ion with AdD receptors 1-4.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Kata Majerski, )
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Marija Luić, )
910-08105-01/243

Ustanove
Institut "Ruđer Bošković", Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


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