High-field/high-frequency EPR of paramagnetic functional centers in Cu2+- and Fe3+-modified polycrystalline Pb[ZrxTi1-x]O-3 ferroelectrics (CROSBI ID 157057)
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Podaci o odgovornosti
Eichel, R. A. ; Meštrić, Hrvoje ; Dinse, K. P. ; Ozarowski, A. ; van Tol, J. ; Brunel, L. C. ; Kungl, H. ; Hoffmann, M. J.
engleski
High-field/high-frequency EPR of paramagnetic functional centers in Cu2+- and Fe3+-modified polycrystalline Pb[ZrxTi1-x]O-3 ferroelectrics
Copper(II)- and iron(III)-modified Pb[ZrxTi1-x]O-3 ferroelectrics were investigated by means of highfield/high-frequency EPR. The results obtained suggest that CU2+ and Fe3+ both substitute as acceptor centers for [ZrTi](4+). Whereas for the iron-doped system the charge compensating oxygen vacancies (VO) lead to the formation of charged (Fe'(Ti)- VO) defect associates, no such associates have been observed for the copper-modified system. As regards the morphotropic phase boundary, the model of a mesoscopic mixing of the pure-member phases has been refined to a picture in which a nanoscale composition distribution prevails.
PbTiO3 single-crystals; electron-spin-resonance; lead titanate; ceramics; ESR; phase; valence; glasses; ions; Cr3+
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Podaci o izdanju
43 (Special Issue)
2005.
S166-S173
objavljeno
0749-1581
10.1002/mrc.1696