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Pregled bibliografske jedinice broj: 421472

Photochemistry of ω -(o-vinylphenyl)-ω '-(phenyl / 2-furyl) butadienes: New approach to 4- substituted benzobicyclo[3.2.1]octadienes


Škorić, Irena; Šmehil, Mario; Marinić, Željko; Molčanov, Krešimir; Kojić-Prodić, Biserka; Šindler-Kulyk, Marija
Photochemistry of ω -(o-vinylphenyl)-ω '-(phenyl / 2-furyl) butadienes: New approach to 4- substituted benzobicyclo[3.2.1]octadienes // Journal of Photochemistry and Photobiology A - Chemistry, 207 (2009), 2; 190-196 (međunarodna recenzija, članak, znanstveni)


Naslov
Photochemistry of ω -(o-vinylphenyl)-ω '-(phenyl / 2-furyl) butadienes: New approach to 4- substituted benzobicyclo[3.2.1]octadienes

Autori
Škorić, Irena ; Šmehil, Mario ; Marinić, Željko ; Molčanov, Krešimir ; Kojić-Prodić, Biserka ; Šindler-Kulyk, Marija

Izvornik
Journal of Photochemistry and Photobiology A - Chemistry (1010-6030) 207 (2009), 2; 190-196

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Cycloaddition; furan; di-pi -methane rearrangement; photochemistry

Sažetak
Novel 1-(o-vinylphenyl)-4-(phenyl/2-furyl) butadienes (4a, b), synthesized in one step, undergo intramolecular photocycloaddition reaction to benzobicyclo[3.2.1]octadiene derivatives (6a, b) in very good yield (70-90%). In the case of phenyl derivative (4a) only endo-phenylbenzobicyclo[ 3.2.1]octadiene isomer (endo-6a) was isolated whereas the furan (4b) derivative resulted in a mixture of endo- and exo-bicyclic isomer (6b). Phenyl benzobicyclo[3.2.1]octadiene derivative (endo-6a) underwent further di-pi-methane rearrangement leading to tricyclic structure (endo-7a). The isolated compound 6a and the product of the rearrangement endo-7a were characterised by X-ray structure analysis.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA


Projekt / tema
098-0982929-2917 - Spektroskopija NMR i modeliranje bioaktivnih molekula (Dejan Plavšić, )
098-1191344-2943 - Protein-ligand međudjelovanja na atomnoj razini (Marija Luić, )
125-0982933-2926 - Heteropolicikli, strukturne osnove za bioaktivne spojeve. Sinteza i fotokemija (Irena Škorić, )

Ustanove
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Uključenost u ostale bibliografske baze podataka:


  • CA Search (Chemical Abstracts)