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Pregled bibliografske jedinice broj: 382338

Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor


Tomašić, Vesna; Jović, Franjo; Gomzi, Zoran
Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor // Catalysis Today, 137 (2008), 2-4; 350-356 (međunarodna recenzija, članak, znanstveni)


CROSBI ID: 382338 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor

Autori
Tomašić, Vesna ; Jović, Franjo ; Gomzi, Zoran

Izvornik
Catalysis Today (0920-5861) 137 (2008), 2-4; 350-356

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Annular photocatalytic reactor; Toluene oxidation; TiO2; Reactor modelling

Sažetak
Photocatalytic oxidation of toluene in the gas phase over UV-illuminated thin layer of titanium dioxide was studied. The reaction was performed in the annular photocatalytic reactor at the room temperature and at various space times. The inlet reacting mixture consisted of air containing toluene and water vapours. Dependence of the reaction rate on various operating variables (water content, inlet toluene concentration and gas flow rate) was examined. The catalytic activity for toluene removal was evaluated by measuring the inlet and outlet toluene concentrations with GC/FID at the steady-state conditions. The additional RD and FTIR measurements were carried out to get better understanding of the catalytic properties. Modelling analysis was carried out to investigate effect of the key parameters on the reactor performance. To understand complex interaction between the chemical reaction and mass transfer phenomena, experimental data were analysed and compared with three different mathematical models (1-D model and 2-D models based on ideal flow and laminar flow conditions). The proposed models were verified by comparing the computer simulation data with the experimental laboratory results. Kinetic constant of the reaction rate, kA, was the adjustable reactor parameter in all models. The results revealed that the reaction rate constant, kA, decreased by increasing the inlet toluene concentrations. At relatively high inlet toluene concentrations the rate of its photocatalytic oxidation became independent of the total flow rate. Relative humidity of the contaminated gas stream had only negligible effect on toluene removal. It was found out that behaviour of the annular photocatalytic reactor was mainly limited by the interphase mass transfer. Finally, the 2-D heterogeneous model, based on the assumed laminar flow through the reactor, appeared to be the most suitable model for a detailed description of the annular photocatalytic reactor used for air pollution remediation.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo



POVEZANOST RADA


Projekti:
125-1251963-1974 - Analiza i modeliranje kemijskih reaktora (Tomašić, Vesna, MZOS ) ( POIROT)

Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb

Profili:

Avatar Url Franjo Jović (autor)

Avatar Url Zoran Gomzi (autor)

Avatar Url Vesna Tomašić (autor)


Citiraj ovu publikaciju:

Tomašić, Vesna; Jović, Franjo; Gomzi, Zoran
Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor // Catalysis Today, 137 (2008), 2-4; 350-356 (međunarodna recenzija, članak, znanstveni)
Tomašić, V., Jović, F. & Gomzi, Z. (2008) Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor. Catalysis Today, 137 (2-4), 350-356.
@article{article, author = {Toma\v{s}i\'{c}, Vesna and Jovi\'{c}, Franjo and Gomzi, Zoran}, year = {2008}, pages = {350-356}, keywords = {Annular photocatalytic reactor, Toluene oxidation, TiO2, Reactor modelling}, journal = {Catalysis Today}, volume = {137}, number = {2-4}, issn = {0920-5861}, title = {Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor}, keyword = {Annular photocatalytic reactor, Toluene oxidation, TiO2, Reactor modelling} }
@article{article, author = {Toma\v{s}i\'{c}, Vesna and Jovi\'{c}, Franjo and Gomzi, Zoran}, year = {2008}, pages = {350-356}, keywords = {Annular photocatalytic reactor, Toluene oxidation, TiO2, Reactor modelling}, journal = {Catalysis Today}, volume = {137}, number = {2-4}, issn = {0920-5861}, title = {Photocatalytic oxidation of toluene in the gas phase: modelling of annular photocatalytic reactor}, keyword = {Annular photocatalytic reactor, Toluene oxidation, TiO2, Reactor modelling} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus


Uključenost u ostale bibliografske baze podataka::


  • Chemical Abstracts
  • Chemical Engineering Abstracts
  • Engineering Informations
  • SCI
  • Scopus
  • Theoretical Engineering Abstracts





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