Change of molecular weight distribution of statistical poly(styrene-co-acrylonitriles) with composition of copolymer (CROSBI ID 147479)
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Podaci o odgovornosti
Mencer, Helena Jasna ; Gomzi, Zoran ; Rogošić, Marko
engleski
Change of molecular weight distribution of statistical poly(styrene-co-acrylonitriles) with composition of copolymer
Statistical poly(styrene-co-acrylonitriles), (SAN) copolymers with varying mole fractions of comonomer units have been synthesized in batch reactor. Intrinsic viscosity and gel permeation chromatography (GPC) pattern of model copolymer samples were the basic experimental results. Chromatographic patterns of SAN copolymer samples were converted into molecular weight distributions and afterwards fitted to the theoretical distribution functions. The correlation between the composition of obtained copolymers and the best fitted model distribution (Schulz's two parameters distribution in this case) was established. The treatment of data shows that parameter (alpha) is inversely proportional to the content of acrylonitrile units in the sample and indicates the present molecular weight interval. Parameter b shows the invariability of the molecular weight distribution shape.
molecular weight distribution; statistical copolymers
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Podaci o izdanju
35 (17)
1995.
1348-1352
objavljeno
0032-3888
1548-2634
10.1002/pen.760351704