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Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines (CROSBI ID 147449)

Prilog u časopisu | izvorni znanstveni rad | međunarodna recenzija

Kobetić, Renata ; Sunko, Dionis Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines // Supramolecular chemistry, 20 (2008), 4; 369-377. doi: 10.1080/10610270701268807

Podaci o odgovornosti

Kobetić, Renata ; Sunko, Dionis

engleski

Hydrolysis of cyclopentenyl-alkyl-N-methyl nicotinates in micelles and cyclodextrines

The formation, via superstructures of a high selectivity was obtained through the ionic interaction, electronic charge-transfer interaction, hydrophobic interaction, and van der Waals interaction in the hydrolysis of iodide-2-( 3-cyclopentenyl)-ethyl-N-methyl-nicotinate, 12, and iodide-3-( 3-cyclopenthenyl)-propyl-N-methyl-nicotinate, 14, in micelles and cyclodextrins. Hydrolysis was accomplished in the aqueous solutions of  - and  - cyclodextrins (CD) and in the aqueous solutions of cetyltrimethylammonium bromide (CTAB). The choice of the leaving group (nicotinate) and the reaction medium influence the reaction rate and the composition of the formed products. Contrary to published data, the hydrolysis of iodide-2-( 3-cyclopenthenyl)-ethyl-N-methyl-nicotinate, 12, in the presence of  -CD yielded endo-2-norborneol.

Hydrolysyis; Cyclopentenyl-alkyl-nicotinates; Cyclodextrines; Micelles; Selectivity

projekt 2.03.01.00.012

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Podaci o izdanju

20 (4)

2008.

369-377

objavljeno

1061-0278

10.1080/10610270701268807

Povezanost rada

Kemija

Poveznice
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